Distribution and Antioxidant Efficiency of Resveratrol in Stripped Corn Oil Emulsions.
نویسندگان
چکیده
We investigated the effects of resveratrol (RES) on the oxidative stability of emulsions composed of stripped corn oil, acidic water and Tween 20 and determined its distribution in the intact emulsions by employing a well-established kinetic method. The distribution of RES is described by two partition constants, that between the oil-interfacial region, PO(I), and that between the aqueous and interfacial region, PW(I). The partition constants, PO(I) and PW(I), are obtained in the intact emulsions from the variations of the observed rate constant, kobs, for the reaction between the hydrophobic 4-hexadecylbenzenediazonium ion and RES with the emulsifier volume fraction, ФI. The obtained PO(I) and PW(I) values are quite high, PW(I) = 4374 and PO(I) = 930, indicating that RES is primarily located in the interfacial region of the emulsions, %RESI > 90% at ФI = 0.005, increasing up to 99% at ФI = 0.04. The oxidative stability of the corn oil emulsions was determined by measuring the formation of conjugated dienes at a given time in the absence and in the presence of RES. The addition of RES did not improve their oxidative stability in spite that more than 90% of RES is located in the interfacial region of the emulsion, because of the very low radical scavenging activity of RES.
منابع مشابه
Stripped corn oil emulsion alters ripening, reduces superficial scald, and reduces core flush in ‘Granny Smith’ apples and decay in ‘d’Anjou’ pears
‘Granny Smith’ apples (Malus x domestica Borkh) and ‘Beurre d’Anjou’ pears (Pyrus communis L.) were dipped in a 2.5, 5, or 10% stripped corn oil (a-tocopherol B5 mg kg) emulsions, 2000 mg l diphenylamine (DPA), respectively, at harvest and stored in air at 0°C for 8 months. Untreated fruit served as controls. In oil-treated apples and pears, ethylene and a-farnesene production rates were lower ...
متن کاملOxidative stability of corn oil with elevated tocotrienols
Oxidation of tocotrienol enriched corn oil was measured for primary oxidative products, lipid hydroperoxides and quantified by peroxide value (PV). Oxidative Stability Index (OSI) was used to determine the induction period (hrs) by indirect measurement of volatile secondary oxidation products, mainly formic acid. Vitamin E stripped corn oil samples were spiked with individual tocotrienols or to...
متن کاملEffect of Salinity, pH, and Temperature on Stability of Gas Condensate in Water Emulsions Using Different Surfactants
Light hydrocarbons in water emulsions are formed in many gas refinery wastewaters, and its stability depends on some parameters such as temperature, pH and salinity. In this study, different surfactants have been used to prepare gas condensates in water emulsion along with four surfactant kinds namely, Span 80, Tween 80, CTAB, SDS and Span 80 and Tween 80 mixture. For this purpose,...
متن کاملInfluence of Salinity, Surfactants and Power of Ultrasonic Homogenizer on Droplet Size Distribution of Crude Oil/Water Emulsions
متن کامل
Antioxidant and free radical-scavenging properties of ethanolic extracts of defatted borage (Borago ocinalis L.) seeds
Borage meal exerted a concentration-dependent antioxidant activity in a meat model system. At 2% (w/w), it inhibited (p 0.05) 2-thiobarbituric acid-reactive substances (TBARS), hexanal and total volatile formation in meat by 26.5, 30.5 and 18.6%, respectively. Antioxidant compounds in the meal were concentrated at optimum extraction conditions (in 52% ethanol at 74 C for 62 min) predicted by re...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Antioxidants
دوره 3 2 شماره
صفحات -
تاریخ انتشار 2014